Here, we present the first demonstration of an important building block in vdW solids: room temperature Esaki tunnel diodes. The structure is two-dimensional and consists of one SnSe2 sheet oriented in the (0, 0, 1) direction. Doping is a vitally important technique that can be used to modulate the properties of two‐dimensional materials. Sn4+ is bonded to six equivalent Se2- atoms to form edge-sharing SnSe6 octahedra. The energy band alignment changes from a staggered gap band offset (type‐II) to a broken gap (type‐III) when changing the negative back‐gate voltage to positive, resulting in the device operating as a rectifier diode (rectification ratio ~10 4) or an n‐type tunneling field effect transistor, respectively. SnSe2 is trigonal omega structured and crystallizes in the trigonal P-3m1 space group. 6, to occur at M and the fundamental band gap of 2.25 eV is between the VBM at Γ and the CBM at L. The valence band is found to be composed of a mixture of S 3p and Sn 5s, while the conduction band consists of a … INTRODUCTION The subthreshold slope (SS) in conventional transistors is limited by thermionic A valence band offset of 0.8 eV, matches the energy gap of SnSe 2 in such a way that the VB edge of WSe 2 and the CB edge of SnSe 2 are lined up, making this materials combination suitable for (nearly) broken gap 2D-2D TFETs. The band gap of SnSe 2 can be tuned from bulk to few-layer thin films with a wide electromagnetic spectrum range (from 1–2 eV). Moreover, both Sn and Se elements are earth-abundant and environmentally friendly, which further makes 2D SnSe2 a potential candidate for optoelectronics. In this work, by using first‐principles density functional calculations, we investigated the electrical properties of SnSe 2 monolayers by p‐type/n‐type and isoelectronic doping. of crystalline C6, n-type SnSe2, at 290 and 77 ?K, have been measured over the photon energy range 0?05-3?7 ev. The optical band gap values of SnSe 2 and … The Esaki diodes were realized in vdW heterostructures made of black phosphorus (BP) and tin diselenide (SnSe2), two layered semiconductors that possess a broken-gap energy band … Two-dimensional SnSe 2 has obvious adjustable band gap characteristics. The calculated gap is in good agreement with the previous calculated result (0.8 eV) , and it is a little larger than the bulk value of 0.71 eV . A band gap is the distance between the valence band of electrons and the conduction band.Essentially, the band gap represents the minimum energy that is required to excite an electron up to a state in the conduction band where it can participate in conduction. The band offset from SnSe2 Fermi level to Al2O3 conduction band minimum is found to be 3.3±0.05 eV and SnSe2 is seen to have a high level of intrinsic electron (n-type) doping with the Fermi level positioned at about 0.2 eV above its conduction band minimum. The optical constants n and ? because of its appropriate indirect band gap (theoretical value of 0.71 eV in bulk material and 0.969 eV monolayer material). All Sn–Se bond lengths are 2.75 Å. Se2- is bonded in a distorted T-shaped geometry to three equivalent Sn4+ atoms. buffer layer. The X-ray diffraction study reveals that as deposited films (SnSe) have orthorhombic crystal structure while the annealed films (SnSe 2) have hexagonal structure. The direct band gap of 2.77 eV can be seen, in Fig. We note that, 1T-ZrS 2 monolayer is an indirect gap (1.1 eV) semiconductor ,while 2H-MoSe 2 and 2H-WSe 2 monolayers have direct wide band gaps of 1.44 eV and 1.56 eV, respectively . 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